Conformational Analysis of Coordination Compounds. III. Tris-diamine Cobalt(III) and Chromium(III) Complexes with Six-membered Chelate Rings.
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چکیده
منابع مشابه
Stereoselective coordination: a six-membered P,N-chelate tailored for asymmetric allylic alkylation.
Six-membered chelate complexes [Pd(1a-b)Cl2], (2a-b) and [Pd(1a-b)(η(3)-PhCHCHCHPh)]BF4, (3a-b) of P,N-type ligands 1a, ((2S,4S)-2-diphenyl-phosphino-4-isopropylamino-pentane) and 1b, ((2S,4S)-2-diphenyl-phosphino-4-methylamino-pentane) have been prepared. The Pd-complexes have been characterized in solution by 1D and 2D NMR spectroscopy. The observed structures were confirmed by DFT calculatio...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1976
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.30a-0485